Code: MSDS # 1780 Preparation date:
Dipropylene Glycol Monobutyl Ether, Safety Technical Instructions CAS No. 29387-86-8 | |||
first | Chemicals and corporate identification | Part 9 | Physical and chemical characteristics |
section two | Risk overview | Part 10 | Stability and reactivity |
part three | Composition/composition information | Part 10 | Toxicology information |
The fourth part | emergency treatment | Part 12 | Ecological information |
The fifth part | fire protection | Part 13 | Waste disposal |
Part VI | Emergency treatment of leakage | Part 14 | Transportation information |
Part 7 | Operational disposal and storage | Part 15 | Regulatory information |
Part 8 | Contact control and individual protection | The sixteenth part | Other information |
Part I: Chemicals and corporate identification | |||
Chinese name: | Dipropylene glycol monobutyl ether | Chinese alias: | non-avaible |
English name : | Dipropylene glycol mono-n- butyl ether | English alias: | non-avaible |
CAS No : | 29911-28-2 | Technical specification code : | MSDS#1780 |
Name of supplier : | Supplier Address: | ||
Suppliers Tel : | Supplier emergency telephone number : | ||
Supplier fax : | Supplier Email : |
Part two: Overview of the danger | |
Risk | non-avaible |
category : | |
route of entry : | Inhalation and feeding into the food for percutaneous absorption |
health hazard: | Excitant to the eyes and to the skin. No cases of poisoning were seen. Anaesthetic effect can be induced at high concentrations. |
environment hazards: | non-avaible |
Fire and explosion danger : | non-avaible |
Part 3: Composition/composition information | |
Hazardous materials: | Dipropylene glycol monobuty1 ether |
content : | 100% |
Part four: First-aid measures | |
skin exposure: | Rinse with running clean water. |
eye contact : | The eyelids were opened and washed with running water for 15 minutes. seek medical advice. |
inhalation: | Leave the scene to the fresh air. Oxygen is given during dyspnea. seek medical advice. |
ingestion: | Mistake, drink the right amount of warm water, vomiting. seek medical advice. |
Part V: Fire protection measures | |
Hazardous characteristics: | In the case of high heat, open fire or oxidant, there is a risk of causing combustion. |
Construction planning and fire risk classification : | non-avaible |
Harmful combustion products: | Carbon monoxide, carbon dioxide. |
Fire extinguishing method: | Fog water, anti-soluble foam, carbon dioxide, dry powder, sand. |
Part VI: Emergency treatment of leakage | |
emergency handling: | Evacuate personnel in the contaminated area to the safe area, and prohibit irrelevant personnel from entering the contaminated area. It is recommended that emergency handling personnel wear masks, goggles and work clothes. Rinse with large amounts of water and dilute it into the wastewater system. It can also be absorbed with sand, shoveled into the bucket, and transported to the waste disposal site. Such as a large number of leakage, the use of embankment shelter, and then collection, transfer, recycling or harmless disposal after waste. |
Part VII: Operation, disposal and storage | |
Operational considerations : | non-avaible |
Storage considerations : | Store in a cool, ventilated storage compartment. Stay away from the fire and heat sources. Packaging shall be sealed and shall not be in contact with the air. Should be stored separately from the oxidant. When handling, light loading and unloading to prevent damage to packaging and containers. Pay attention to the packing and handling operations for personal protection. |
Part 8: Contact control / personal protection | |
China MAC (mg/m3) : | non-avaible |
Former Soviet | non-avaible |
Union MAC (mg/m3) : | |
TLVTN: | non-avaible |
TLVWN: | non-avaible |
exposure limit : | US TLV-TWA: No standards developed US TLV-STEL: No standards developed |
Monitoring method: | non-avaible |
engineering control: | Closed operation, pay attention to ventilation. |
Respiratory System Protection: | At high concentrations in the air, wear a mask respirator. |
eye protection : | Wear safety protection glasses. |
Body protection : | Wear work clothes. |
Hand protection : | Wear protective gloves. |
Other protection : | non-avaible |
Part 9: Physical and chemical characteristics | |||
pH: | non-avaible | melting point | non-avaible |
(℃) : | |||
boiling point | 214~217 | molecular formula: | C10H22O3 |
(℃) : | |||
basis: | non-avaible | Saturation vapor pressure (kPa) : | 0.00798/25℃ |
Octanol/water partition coefficient : | non-avaible | critical | non-avaible |
temperatures (℃): | |||
flash point (℃): | 96 | ignition | non-avaible |
temperature (℃) : | |||
autogenous ignition | non-avaible | combustibility: | combustible |
temperature: | |||
solubility: | dissolve in water. | Relative density (water =1) : | 0.913 |
Relative vapor density (air =1) : | non-avaible | formula weight: | 190.32 |
Heat of | non-avaible | Critical | non-avaible |
combustion (kJ / mol) : | Pressure (MPa): | ||
Bblast% (V / V) : | non-avaible | Lower limit% (V / V) : | non-avaible |
Appearance and traits : | Colorless liquid. | ||
main application : | For the organic synthesis. | ||
Other physical and chemical properties : | non-avaible | ||
Part X: Stability and reactivity | |
stability : | stabilize |
Prohibited: | Strong oxidant. |
Conditions to avoid contact: | non-avaible |
Polymerization hazard: | Cant appear |
cleavage product: | non-avaible |
Part X: Toxicology information | |
acute toxicity: | LD50:2 ml/kg (rat mouth) LC50 : |
Subacute and chronic toxicity: | non-avaible |
RTECS: | UA8200000 |
thrill: | non-avaible |
sensitization: | non-avaible |
mutagenicity: | non-avaible |
teratogenicity: | non-avaible |
carcinogenicity: | non-avaible |
Part XII: Ecological data | |
Eco- | non-avaible |
toxicological toxicity: | |
biodegradability: | non-avaible |
Non-biological degradability: | non-avaible |
Biological enrichment or bioaccumulability: | non-avaible |
Other harmful effects: | After work, take a shower and change your clothes. Pay attention to personal hygiene. |
Part 13: Waste disposal | |
Waste property : | Reference to relevant national and local laws and regulations before disposal. It is recommended to dispose of it by incineration method. |
Waste disposal method: | non-avaible |
Waste considerations : | non-avaible |
Part 14 : Transportation information | |
Dangerous Goods No. : | non-avaible |
Synonyms | Propylene glycol n-butyl ether; 3-Butoxypropan-2-ol; propylene glycol monobutyl ether. |
Chemical Formula | C4H9OCH2CH(CH3)OH (major isomer) |
Product Description | DOWANOL™ PnB Glycol Ether is a fast-evaporating, hydrophobic glycol ether with high solvency and excellent coupling abilities. DOWANOL™ PnB Glycol Ether is extensively used in heavy-duty cleaning formulations. It does an excellent job of solvating and coupling hydrophobic greases and oils in household as well as industrial formulations. It is partly water soluble and miscible with most organic solvents. DOWANOL™ PnB Glycol Ether also provides excellent surface-tension lowering ability. In coatings DOWANOL™ PnB Glycol Ether offers good coalescing ability in systems requiring fast evaporation. |
Applications |
|
Typical Properties
Specification Writers: These values are not intended for use in preparing specifications.
Property | Unit | Result |
Molecular Weight | g/mol | 132.2 |
Boiling Point @ 760 mmHg, 1.01 ar | °C (°F) | 171 (340) |
Flash Point (Setaflash Closed Cup) | °C (°F) | 63 (145) |
Freezing Point | °C (°F) | < -80 (< -112) |
Vapor Pressure @ 20°C — Extrapolated | mmHg hPA | 0.85 (1.05 @ 25°C) 1.39 |
Specific Gravity (20/20°C) | 0.878 | |
Liquid Density @ 20°C | g/cm3 | 0.879 |
@ 25°C | g/cm3 | 0.875 |
Typical Properties (Cont.)
Property | Unit | Result |
Vapor Density (air = 1) | 4.6 | |
Viscosity | cP or mPa•s @ 25°C | 2.8 |
Surface Tension | dynes/cm or mN/m @ 20°C | 27.5 |
Specific Heat | J/g/°C @ 25°C | 1.98 |
Heat of Vaporization at Normal Boiling Point | J/g | 320 |
Net Heat of Combustion — Predicted @ 25°C | 31.4 | |
Autoignition Temperature | °C (°F) | 260 (500) |
Evaporation Rate (N-butyl Acetate = 1.0) | 0.093 | |
Solubility, g/L or % @ 20°C | ||
Solvent in Water | g/L | 52 |
Hansen Solubility Parameters _d (Dispersion) _p (Polar) _h (Hydrogen Bonding) | (J/cm3)1/2 | 14.9 4.9 10.7 |
Partition Coefficient, N-octonol/Water (Log Pow) | 1.2 | |
Flammable Limits (Vol.% in Air) | ||
Lower | 1.1 | |
Upper | 8.4 |
Classification/ Registry Numbers/Country Inventory1
CAS# | 5131-66-8 |
AICS (Australia) | 5131-66-8 |
DSL (Canada) | 5131-66-8 |
IECSC (China) | 5131-66-8 |
ECI (Korea) | 5131-66-8/KE-04165 |
EINECS (EU) | 225-878-4 |
MITI (Japan) | 5131-66-8 |
ENCS/IHSL (Japan) | 2-2424 |
NZIoC (New Zealand) | 5131-66-8/HSR001419 |
PICCS (Philippines) | 5131-66-8 |
TSCA (U.S.) | 5131-66-8 |
1NOTE: Classifications apply only to this glycol ether product. It is the responsibility of the formulator to ensure that the final finished product complies with the regulations of a given country prior to its sale or distribution in that country.
How Supplied
REGION | PACKAGING | TRANSPORT MODE |
Europe/Africa | Bulk/Drum | Tank Truck |
Latin America | Bulk/Drum | Tank Truck |
North America | Bulk/Drum | Tank Truck/Tank Car |
Pacific | Bulk/Drum | Tank Truck |
Handling Precautions
PRODUCT SAFETY INFORMATION REQUIRED FOR SAFE USE IS NOT INCLUDED IN THIS DOCUMENT. BEFORE HANDLING, READ PRODUCT AND SAFETY DATA SHEETS AND CONTAINER LABELS FOR SAFE USE, PHYSICAL AND HEALTH HAZARD INFORMATION. THE SAFETY DATA SHEET IS AVAILABLE ON THE DOW WEBSITE AT DOW.COM, OR FROM YOUR DOW SALES APPLICATION ENGINEER, OR DISTRIBUTOR, OR BY CALLING DOW CUSTOMER SERVICE.
Limitations This product is neither tested nor represented as suitable for medical or pharmaceutical uses.
Health and Environmental Information
To support customers in their product safety needs, Dow has an extensive Product Stewardship organization and a team of product safety and regulatory compliance specialists available in each area. For further information, please see our website, dow.com or consult your local Dow representative.
Disposal Considerations
Dispose in accordance with all local, state (provincial) and federal regulations. Empty containers may contain hazardous residues. This material and its container must be disposed in a safe and legal manner. It is the user’s responsibility to verify that treatment and disposal procedures comply with
local, state (provincial) and federal regulations. Contact your Dow Technical Representative for more information.
Product Stewardship
Dow has a fundamental concern for all who make, distribute, and use its products, and for the environment in which we live. This concern is the basis for our product stewardship philosophy by which we assess the safety, health, and environmental information on our products and then take appropriate steps to protect employee and public health and our environment. The success of our product stewardship program rests with each and every individual involved with Dow products - from the initial concept and research, to manufacture, use, sale, disposal, and recycle of each product.
Customer Notice
Dow strongly encourages its customers to review both their manufacturing processes and their applications of Dow products from the standpoint of human health and environmental quality to ensure that Dow products are not used in ways for which they are not intended or tested. Dow personnel are available to answer your questions and to provide reasonable technical support. Dow product literature, including safety data sheets, should be consulted prior to use of Dow products. Current safety data sheets are available from Dow.
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