Guangzhou Eric Wei Chemical Co., Ltd.
Guangzhou Eric Wei Chemical Co., Ltd.

PNB (Propylene Glycol Butyl Ether)

Description

A low-toxicity, high-boiling point suitable for paints and inks.


CAS No.

CAS No. 29387-86-8



  • pnb-propylene-glycol-butyl-ether
  • pnb-propylene-glycol-butyl-ether-dow
  • pnb-propylene-glycol-butyl-ether
  • pnb-propylene-glycol-butyl-ether-dow

Code: MSDS # 1780 Preparation date:

Dipropylene Glycol Monobutyl Ether, Safety Technical Instructions CAS No. 29387-86-8

first

Chemicals and corporate identification

Part 9

Physical and chemical characteristics

section two

Risk overview

Part 10

Stability and reactivity

part  three

Composition/composition information

Part 10

Toxicology information

The

fourth part

emergency treatment

Part 12

Ecological information

The

fifth part

fire protection

Part 13

Waste disposal

Part VI

Emergency treatment of leakage

Part 14

Transportation information

Part 7

Operational disposal and storage

Part 15

Regulatory information

Part 8

Contact control and individual protection

The

sixteenth part

Other information

Part I: Chemicals and corporate identification

Chinese name:

Dipropylene glycol monobutyl ether

Chinese alias:

non-avaible

English name :

Dipropylene glycol mono-n- butyl ether

English alias:

non-avaible

CAS No :

29911-28-2

Technical

specification code :

MSDS#1780

Name of

supplier :


Supplier Address:


Suppliers Tel :


Supplier  emergency telephone number :


Supplier fax :


Supplier Email :


Part two: Overview of the danger
Risknon-avaible
category :
route of entry :Inhalation and feeding into the food for percutaneous absorption
health  hazard:Excitant to the eyes and to the skin. No cases of poisoning were seen. Anaesthetic effect can be induced at high concentrations.
environment hazards:non-avaible
Fire and  explosion danger :non-avaible

Part 3: Composition/composition information

Hazardous  materials:

Dipropylene glycol monobuty1 ether

content :

100%

Part four: First-aid measures

skin exposure:

Rinse with running clean water.

eye contact :

The eyelids were opened and washed with running water for 15 minutes. seek medical advice.

inhalation:

Leave the scene to the fresh air. Oxygen is given during dyspnea. seek medical advice.

ingestion:

Mistake, drink the right amount of warm water, vomiting. seek medical advice.


Part V: Fire protection measures
Hazardous characteristics:In the case of high heat, open fire or oxidant, there is a risk of causing combustion.
Construction planning and fire risk classification :non-avaible
Harmful combustion products:Carbon monoxide, carbon dioxide.
Fire extinguishing method:Fog water, anti-soluble foam, carbon dioxide, dry powder, sand.

Part VI: Emergency treatment of leakage



emergency handling:

Evacuate personnel in the contaminated area to the safe area, and prohibit irrelevant personnel from entering the contaminated area. It is recommended that emergency handling personnel wear masks, goggles and work clothes. Rinse with large amounts of water and dilute it into the wastewater system. It can also be absorbed with sand, shoveled into the bucket, and transported to the waste disposal site. Such as a large number of leakage, the use of embankment shelter, and then collection, transfer, recycling or harmless disposal after waste.

Part VII: Operation, disposal and storage

Operational considerations :

non-avaible

Storage considerations :

Store in a cool, ventilated storage compartment. Stay away from the fire and heat sources. Packaging shall be sealed and shall not be in contact with the air. Should be stored separately from the oxidant. When handling, light loading and unloading to prevent damage to packaging and containers. Pay attention to the packing and handling operations for personal protection.

Part 8: Contact control / personal protection
China MAC (mg/m3) :non-avaible
Former Sovietnon-avaible
Union MAC (mg/m3) :
TLVTN:non-avaible
TLVWN:non-avaible
exposure limit :US TLV-TWA: No standards developed US TLV-STEL: No standards developed
Monitoring method:non-avaible
engineering control:Closed operation, pay attention to ventilation.
Respiratory System Protection:At high concentrations in the air, wear a mask respirator.
eye protection :Wear safety protection glasses.
Body protection :Wear work clothes.
Hand protection :Wear protective gloves.
Other protection :non-avaible


Part 9: Physical and chemical characteristics
pH:non-avaiblemelting pointnon-avaible
(℃) :
boiling point214~217molecular formula:C10H22O3
(℃) :
basis:non-avaibleSaturation vapor pressure (kPa) :0.00798/25℃
Octanol/water partition coefficient :non-avaiblecriticalnon-avaible
temperatures (℃):
flash point (℃):96ignitionnon-avaible
temperature (℃) :
autogenous ignitionnon-avaiblecombustibility:combustible
temperature:
solubility:dissolve in water.Relative density (water =1) :0.913
Relative vapor density (air =1) :non-avaibleformula weight:190.32
Heat ofnon-avaibleCriticalnon-avaible
combustion (kJ / mol) :Pressure (MPa):
Bblast% (V / V) :non-avaibleLower limit% (V / V) :non-avaible
Appearance  and traits :Colorless liquid.
main application :For the organic synthesis.
Other physical and chemical properties :non-avaible

Part X: Stability and reactivity

stability :

stabilize

Prohibited:

Strong oxidant.

Conditions to  avoid contact:

non-avaible

Polymerization hazard:

Cant appear

cleavage product:

non-avaible

Part X: Toxicology information

acute

toxicity:

LD50:2 ml/kg (rat mouth) LC50 :

Subacute and

chronic toxicity:

non-avaible

RTECS:

UA8200000

thrill:

non-avaible

sensitization:

non-avaible

mutagenicity:

non-avaible

teratogenicity:

non-avaible

carcinogenicity:

non-avaible

Part XII: Ecological data
Eco-non-avaible
toxicological toxicity:
biodegradability:non-avaible
Non-biological degradability:non-avaible
Biological enrichment or bioaccumulability:non-avaible
Other harmful effects:After work, take a shower and change your clothes. Pay attention to personal hygiene.

Part 13: Waste disposal

Waste

property :

Reference to relevant national and local laws and regulations before disposal. It is recommended to dispose of it by incineration method.

Waste disposal method:

non-avaible

Waste

considerations :

non-avaible


Part 14 : Transportation information

Dangerous  Goods No. :

non-avaible



Dowanol™ Pnb Glycol Ether CAS No. 29387-86-8


Synonyms


Propylene glycol n-butyl ether; 3-Butoxypropan-2-ol; propylene glycol monobutyl ether.

Chemical Formula

C4H9OCH2CH(CH3)OH (major isomer)

Product

Description

DOWANOL™ PnB Glycol Ether is a fast-evaporating, hydrophobic glycol ether with high

solvency and excellent coupling abilities. DOWANOL™ PnB Glycol Ether is extensively

used in heavy-duty cleaning formulations. It does an excellent job of solvating and coupling hydrophobic greases and oils in household as well as industrial formulations. It is partly

water soluble and miscible with most organic solvents. DOWANOL™ PnB Glycol Ether also provides excellent surface-tension lowering ability. In coatings DOWANOL™ PnB Glycol

Ether offers good coalescing ability in systems requiring fast evaporation.

Applications

  • Coupling agent and solvent in household and industrial cleaners, grease and paint removers, metal cleaners, and hard surface cleaners.

  • Effective coupling agent and efficient solvent for water-reducible coatings.

  • Effective coalescent for lowering minimum film formation temperature (MFFT) in water- borne latex coatings.

  • Active solvent for solvent-based coatings.

  • Chemical intermediate for the production of epoxides, acid ester derivatives, solvents, and plasticizers.

  • Effective coupling agent in waterbased agricultural formulations.


Typical Properties

Specification Writers: These values are not intended for use in preparing specifications.

Property

Unit

Result

Molecular Weight

g/mol

132.2

Boiling Point @ 760 mmHg, 1.01 ar

°C (°F)

171 (340)

Flash Point (Setaflash Closed Cup)

°C (°F)

63 (145)

Freezing Point

°C (°F)

< -80 (< -112)

Vapor Pressure @ 20°C — Extrapolated

mmHg hPA

0.85 (1.05 @ 25°C) 1.39

Specific Gravity (20/20°C)


0.878

Liquid Density @ 20°C

g/cm3

0.879

@ 25°C

g/cm3

0.875


Typical Properties (Cont.)

Property

Unit

Result

Vapor Density (air = 1)


4.6

Viscosity

cP or mPa•s @ 25°C

2.8

Surface Tension

dynes/cm or mN/m @ 20°C

27.5

Specific Heat

J/g/°C @ 25°C

1.98

Heat of Vaporization at Normal Boiling Point

J/g

320

Net Heat of Combustion — Predicted @ 25°C


31.4

Autoignition Temperature

°C (°F)

260 (500)

Evaporation Rate (N-butyl Acetate = 1.0)


0.093

Solubility, g/L or % @ 20°C



Solvent in Water

g/L

52

Hansen Solubility Parameters _d (Dispersion)

_p (Polar)

_h (Hydrogen Bonding)

(J/cm3)1/2


14.9 4.9   10.7

Partition Coefficient, N-octonol/Water (Log Pow)


1.2

Flammable Limits (Vol.% in Air)



Lower


1.1

Upper


8.4


Classification/ Registry Numbers/Country Inventory1

CAS#

5131-66-8

AICS (Australia)

5131-66-8

DSL (Canada)

5131-66-8

IECSC (China)

5131-66-8

ECI (Korea)

5131-66-8/KE-04165

EINECS (EU)

225-878-4

MITI (Japan)

5131-66-8

ENCS/IHSL (Japan)

2-2424

NZIoC (New Zealand)

5131-66-8/HSR001419

PICCS (Philippines)

5131-66-8

TSCA (U.S.)

5131-66-8

1NOTE: Classifications apply only to this glycol ether product. It is the responsibility of the formulator to ensure that the final finished product complies with the regulations of a given country prior to its sale or distribution in that country.


How Supplied

REGION

PACKAGING

TRANSPORT MODE

Europe/Africa

Bulk/Drum

Tank Truck

Latin America

Bulk/Drum

Tank Truck

North America

Bulk/Drum

Tank Truck/Tank Car

Pacific

Bulk/Drum

Tank Truck


Handling Precautions

PRODUCT SAFETY INFORMATION REQUIRED FOR SAFE USE IS NOT INCLUDED IN THIS DOCUMENT. BEFORE HANDLING, READ PRODUCT AND SAFETY DATA SHEETS AND CONTAINER LABELS FOR SAFE USE, PHYSICAL AND HEALTH HAZARD INFORMATION. THE SAFETY DATA SHEET IS AVAILABLE ON THE DOW WEBSITE AT DOW.COM, OR FROM YOUR DOW SALES APPLICATION ENGINEER, OR DISTRIBUTOR, OR BY CALLING DOW CUSTOMER SERVICE.

Limitations This product is neither tested nor represented as suitable for medical or pharmaceutical uses.


Health and Environmental Information

To support customers in their product safety needs, Dow has an extensive Product Stewardship organization and a team of product safety and regulatory compliance  specialists available in each area. For further information, please see our website, dow.com or consult your local Dow representative.


Disposal Considerations

Dispose in accordance with all local, state (provincial) and federal regulations. Empty containers may contain hazardous residues. This material and its container must be  disposed in a safe and legal manner. It is the user’s responsibility to verify that treatment and disposal procedures comply with

local, state (provincial) and federal regulations. Contact your Dow Technical Representative for more information.


Product Stewardship

Dow has a fundamental concern for all who make, distribute, and use its products, and for the environment in which we live. This concern is the basis for our product stewardship philosophy by which we assess the safety, health, and environmental information on our  products and then take appropriate steps to protect employee and public health and our   environment. The success of our product stewardship program rests with each and every individual involved with Dow products - from the initial concept and research, to manufacture, use, sale, disposal, and recycle of each product.


Customer Notice

Dow strongly encourages its customers to review both their manufacturing processes and   their applications of Dow products from the standpoint of human health and environmental  quality to ensure that Dow products are not used in ways for which they are not intended or tested. Dow personnel are available to answer your questions and to provide reasonable technical support. Dow product literature, including safety data sheets, should be consulted prior to use of Dow products. Current safety data sheets are available from Dow.


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